How about trading Skype names and forming a Blender support desk?
When using Blender you're obviously on your computer, and probably connected to the internet. If you run into a problem usually you have to come to the forums and start a thread, then wait for a reply. But so many times I've had a little problem that's not thread worthy and just wish there was someone I could call/text/message to help clear it up. This will allow that! Skype allows you to send screenshots, files (.blends anyone?), chat, text, conference calls and more!
If anyone wants to join the support desk, please add your details in the article comments here, or in the blenderartist's thread, and I'll make sure your name is put on the list.
I think this is a great initiative. I don't have any burning questions right now, but give this a try and let us know how it worked for you!
Check out the thread on BlenderArtists for a current list of BlenderSkype supporters.