German trainer Helge Maus has released a Blender 2.5 training DVD. It contains 11 chapters and in over 12 hours of video, and looks like a solid piece of work. You can watch a 7-minute free sample, 'Modeling a Flag' online (in German, of course). The DVD is priced at €39,90.
I have a LONG history with Blender - I wrote some of the earliest Blender tutorials, worked for Not a Number and helped run the crowdfunding campaign that open sourced Blender (the first one on the internet!). I founded BlenderNation in 2006 and have been editing it every single day since then ;-) I also run the Blender Artists forum and I'm Head of Community at Sketchfab.